Sodium Chlorodifluoroacetate TCI C0991

Chemical Identity

Other names: Chlorodifluoroacetic Acid Sodium Salt
CAS No.: 1895-39-2
Formula: C2ClF2NaO2
Molecular weight: 152.46 g/mol
Purity: >99.0%(T)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: sodium 2-chloro-2,2-difluoroacetate
SMILES: C(=O)(C(F)(F)Cl)[O-].[Na+]
InChIKey: MRTAVLDNYYEJHK-UHFFFAOYSA-M
MDL: MDL00064771
PubChem: CID 2734985

Rp 1.510.950,00

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Berat 25g 100g

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TCI C0991 Sodium Chlorodifluoroacetate (CAS 1895-39-2) is a solid fluorinated building block widely used as an in-situ difluorocarbene source. On heating it enables gem-difluorocyclopropanation of alkenes and difluoromethylation of nucleophiles such as phenols, thiols and amines. AMI Scientific offers this TCI product in 25 g, 100 g and 500 g pack sizes to suit exploratory through repeated synthetic work. Keep the container tightly closed, ensure adequate venting during heated reactions, and follow the manufacturer's label and safety data sheet.

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Mehta et al. (2014). ChemInform Abstract: S‐, N‐, and Se‐Difluoromethylation Using Sodium Chlorodifluoroacetate.. ChemInform doi:10.1002/chin.201410085
Mehta et al. (2013). S-, N-, and Se-Difluoromethylation Using Sodium Chlorodifluoroacetate. Organic Letters doi:10.1021/ol402370f
Williams et al. (2015). ChemInform Abstract: Mild Chlorodifluoroacylation of Indoles via Self‐Activation of Sodium Chlorodifluoroacetate.. ChemInform doi:10.1002/chin.201505133

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.