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TCI

CAS 39262-22-1

(-)-10-Camphorsulfonyl Chloride TCI C1308

(-)-10-Camphorsulfonyl Chloride TCI C1308

Chemical Identity

CAS No.
39262-22-1
PubChem
CID 9816396·SID 87566322
Formula
C10H15ClO3S
Molecular weight
250.74 g/mol
Purity
>98.0%(T)
Storage
0-10°C
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
[(1R,4S)-7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl]methanesulfonyl chloride
SMILES
CC1(C2CCC1(C(=O)C2)CS(=O)(=O)Cl)C
InChIKey
BGABKEVTHIJBIW-XVKPBYJWSA-N
MDL
MDL00064155
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TCI C1308 (-)-10-Camphorsulfonyl Chloride is a chiral sulfonyl chloride built on the rigid, optically active camphor skeleton. Its highly reactive sulfonyl chloride group readily couples with amines and alcohols to give sulfonamides and sulfonate esters under mild conditions. Researchers commonly use it to prepare camphor-derived chiral auxiliaries and ligands, and as a derivatizing reagent for enantiomeric analysis. Supplied by AMI Scientific in 5 g and 25 g packs, it should be kept dry and tightly closed because of its sensitivity to moisture.

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  • KO et al. (1998). ChemInform Abstract: A Convenient Preparation of (1S)‐(+)‐10‐Mercaptoisoborneol from (1S)‐(+)‐10‐Camphorsulfonyl Chloride with High Diastereoselectivity.. ChemInform doi:10.1002/chin.199837217

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.