TCI C1363 (-)-2-Cyano-6-phenyloxazolopiperidine (CAS 88056-92-2) is a bicyclic chiral synthon designed for the asymmetric synthesis of piperidine alkaloids. Its alpha-aminonitrile function is remarkably versatile: deprotonation generates a stabilised carbanion for reaction with electrophiles, while loss of cyanide delivers an iminium ion that reacts with nucleophiles. The chiral oxazolidine framework controls the facial approach of incoming reagents, giving substituted piperidines with high diastereoselectivity before the auxiliary is removed. AMI Scientific supplies this TCI chiral building block in a 1 g pack size for asymmetric synthesis research.
TCI brochures (PDF)
- Chiral Building Blocks 2025-04-14 · p. 5
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Produk Terkait
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1-[(Trifluoromethyl)sulfonyl]piperidine TCI T4342
Regular price From Rp 2.942.100,00Regular priceRp 2.072.700,00Sale price From Rp 2.942.100,00 -
tert-Butyl4-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazol-1-yl]piperidine-1-carboxylate TCI B5002
Regular price From Rp 1.749.300,00Regular priceRp 1.239.000,00Sale price From Rp 1.749.300,00 -
tert-Butyl4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)piperidine-1-carboxylate TCI D6579
Regular price Rp 2.411.850,00Regular priceRp 1.702.050,00Sale price Rp 2.411.850,00 -
tert-Butyl4-(Piperazin-1-ylmethyl)piperidine-1-carboxylate TCI D5966
Regular price From Rp 1.563.450,00Regular priceRp 1.108.800,00Sale price From Rp 1.563.450,00 -
tert-Butyl5'-Fluoro-1',4'-dihydro-2'H-spiro[piperidine-4,3'-quinoline]-1-carboxylate TCI B6777
Regular price Rp 7.234.500,00Regular priceRp 5.074.650,00Sale price Rp 7.234.500,00 -
tert-Butyl7'-Fluoro-1',4'-dihydro-2'H-spiro[piperidine-4,3'-quinoline]-1-carboxylate TCI B6776
Regular price Rp 7.234.500,00Regular priceRp 5.074.650,00Sale price Rp 7.234.500,00 -
BenzylSpiro[indoline-3,4'-piperidine]-1'-carboxylate TCI B5847
Regular price Rp 7.578.900,00Regular priceRp 5.315.100,00Sale price Rp 7.578.900,00
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