• 1,1'-Thiocarbonyldiimidazole (CAS 6160-65-2) - TCI C1376 - AMI Scientific
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TCI

CAS 6160-65-2

1,1'-Thiocarbonyldiimidazole TCI C1376

1,1'-Thiocarbonyldiimidazole TCI C1376
Rp 1.476.300,00
Rp 1.476.300,00
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TCI C1376 1,1'-Thiocarbonyldiimidazole (TCDI, CAS 6160-65-2) is a versatile thiocarbonyl transfer reagent for organic synthesis. It is best known for converting alcohols into thiocarbonyl imidazolides, the key step of the Barton–McCombie radical deoxygenation. The reagent is also used to prepare isothiocyanates, thioureas, thiocarbamates, and cyclic thiocarbonates from diols. Because it is moisture sensitive, AMI Scientific recommends storing this TCI product tightly sealed in a cool, dry place; 5 g and 25 g packs are available.

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  • March et al. (2024). Mechanistic Studies of Imidazole Autocatalysis in 1,1′-Thiocarbonyldiimidazole-Mediated Couplings of Aniline. Organic Process Research & Development doi:10.1021/acs.oprd.4c00098
  • Paul-Gorsline (2024). Development of a Mechanism-Based Kinetic Model and Process Optimization Incorporating Imidazole Autocatalysis in a 1,1′-Thiocarbonyldiimidazole-Mediated Thiocarbonyl Transfer. Organic Process Research & Development doi:10.1021/acs.oprd.4c00099
  • Zarei et al. (2013). ChemInform Abstract: Synthesis of β‐Lactams from Acids and Imines Using Thiocarbonyldiimidazole.. ChemInform doi:10.1002/chin.201321101

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.

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