• 1-Chloroethyl Chloroformate (CAS 50893-53-3) - TCI C1395 - AMI Scientific
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TCI

CAS 50893-53-3

1-Chloroethyl Chloroformate TCI C1395

1-Chloroethyl Chloroformate TCI C1395
Rp 1.326.150,00
Rp 1.326.150,00
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TCI C1395 1-Chloroethyl Chloroformate (CAS 50893-53-3), often abbreviated ACE-Cl, is a highly reactive chloroformate reagent for amine chemistry. It is best known for the selective demethylation of tertiary amines, proceeding through a 1-chloroethyl carbamate that is cleaved on heating in methanol. The reagent is also used to install carbamate protecting groups and to prepare carbonate-based prodrug intermediates. AMI Scientific offers 25 g and 250 g packs; the material is moisture-sensitive and should be handled with anhydrous technique in a fume hood.

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  • Yang et al. (1993). Mild and Selective Debenzylation of Tertiary Amines Using α-Chloroethyl Chloroformate. Synlett doi:10.1055/s-1993-22398
  • Pelander et al. (1997). Preparation of N-demethylated drug metabolites for analytical purposes using 1-chloroethyl chloroformate. Forensic Science International doi:10.1016/s0379-0738(96)02088-9
  • YANG et al. (1994). ChemInform Abstract: Mild and Selective Debenzylation of Tertiary Amines, e.g. (I), (V), Using α‐Chloroethyl Chloroformate (II).. ChemInform doi:10.1002/chin.199421095

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.

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