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Description
TCI H0060 Hexachloroethane is a simple organochlorine compound built from two carbon atoms whose every available position is occupied by a chlorine atom, giving a total of six chlorine substituents on an ethane skeleton. The material appears as a white crystalline solid with the distinctive property of subliming readily, passing directly from the solid state to vapour without going through a liquid phase under ordinary conditions. In the laboratory it serves as a chlorine source in certain chlorination reactions, as a comparison compound in the analysis of chlorinated organic substances, and as a model compound in environmental research concerned with the behaviour and degradation of organochlorine pollutants.
The property that governs its use is the complete chlorine saturation of the ethane framework. With no hydrogen atoms present at all, the compound is not flammable and remains relatively stable towards many common reagents, yet its carbon–chlorine bonds can be exploited as a chlorine atom transfer agent in selected organic reactions. The tendency to sublime means the material must be kept in genuinely tight containers, while the same tendency conveniently allows purification by sublimation. Its solubility is good in non-polar organic solvents but very low in water, a characteristic directly relevant to studies of partitioning and pollutant transport in the environment.
In Indonesian laboratories, this compound is typically encountered in university and research-institute settings where synthetic organic chemistry, analytical method development, and environmental studies are carried out. It is used where a fully chlorinated reference material or a defined chlorine-transfer reagent is required, and it supports environmental work on the fate of organochlorine compounds. Supplied under the TCI brand, it fits routine bench-scale use in teaching and research contexts alike.
Laboratory Applications
Chlorination reactions in organic synthesis, where the fully chlorine-saturated ethane skeleton acts as a chlorine source and its carbon–chlorine bonds function as chlorine atom transfer sites in selected transformations.
Reference material in the analysis of chlorinated organic compounds, serving as a comparison substance so that analysts can benchmark the response and identification of related chlorinated species.
Model compound in environmental research, allowing investigators to study the behaviour and degradation pathways of organochlorine pollutants under controlled and reproducible laboratory conditions.
Partitioning and transport studies, since the compound's good solubility in non-polar organic solvents together with very low water solubility makes it suitable for examining pollutant distribution between phases.
Purification practice and demonstration by sublimation, because the material's tendency to pass directly from solid to vapour makes it a practical subject for sublimation-based purification and technique training.
Specifications
Brand: TCI
CAS number: 67-72-1
Category: Chemistry > Building Blocks > Non-Heterocyclic Building Blocks
Pack sizes: available in standard TCI catalogue pack sizes; please confirm the size required when ordering
Physical form: white crystalline solid that sublimes readily
Storage note: keep in a tightly closed container to limit loss by sublimation
Handling and Storage
Store the material in a tightly closed container, since its tendency to sublime means that loosely sealed packaging will allow gradual loss of solid as vapour. Keep containers in a cool, dry place away from incompatible reagents, and close them promptly after each use. Handle the solid in a well-ventilated area or fume hood to avoid inhalation of any vapour formed, and use standard laboratory personal protective equipment including gloves, safety glasses, and a laboratory coat. Although the compound contains no hydrogen and is therefore not flammable, it should still be treated as a chlorinated organic material, with residues and waste collected separately according to the laboratory's halogenated waste procedures.
