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Description
Methyl Hexanoate is the methyl ester of hexanoic acid and the simplest member of the hexanoate ester series. It holds a particular place in the laboratory because it belongs to the medium-chain fatty acid methyl esters (FAME), the derivative form routinely prepared when fatty acids are analysed by gas chromatography. Beyond its role as an analytical standard compound, this material is also used as a synthesis intermediate and as a reference compound in food aroma studies that trace volatile esters.
The property that makes Methyl Hexanoate a frequent choice is its volatility, which is the highest among comparable hexanoate esters because of the small methyl group on the alcohol portion of the molecule. This characteristic shortens retention time and produces sharp, well-defined peaks in gas chromatographic analysis. The compound is a liquid with a fruity aroma, dissolving readily in organic solvents but only very sparingly in water. Its methyl ester group undergoes transesterification and hydrolysis relatively easily, making it a practical starting point for forming other ester derivatives or for converting the material back to hexanoic acid.
In Indonesian laboratories, this material is widely encountered wherever fatty acid methyl esters and volatile esters are studied. It supports chromatographic work in analytical service laboratories, teaching laboratories, and research groups, where a well-behaved medium-chain ester is needed as a comparison compound or as a convenient building block for further ester chemistry.
Laboratory Applications
Gas chromatography reference standard: its high volatility and short retention time give sharp, easily identified peaks that anchor the medium-chain region of a FAME chromatogram.
Fatty acid methyl ester analysis: as a medium-chain FAME it represents the derivative form fatty acids are converted into before chromatographic separation and identification work.
Food aroma and flavour research: the fruity-smelling compound serves as a comparison standard when volatile esters contributing to aroma profiles are being traced and characterised.
Organic synthesis intermediate: the reactive methyl ester group provides a practical entry point for building further compounds through established ester transformation chemistry routes.
Transesterification and hydrolysis studies: its ester group reacts readily, allowing conversion into other ester derivatives or reversion back to hexanoic acid for methodology work.
Specifications
Brand: TCI
CAS number: 106-70-7
Catalogue code: H0111
Category: Chemistry > Building Blocks > Non-Heterocyclic Building Blocks
Physical form: liquid with a fruity aroma; soluble in organic solvents, very limited solubility in water
Pack sizes: available in standard TCI laboratory pack sizes — please confirm the size required when ordering
Storage: keep in a tightly closed container in a cool, well-ventilated place
Handling and Storage
Store Methyl Hexanoate in a tightly closed container in a cool, dry, and well-ventilated area, away from heat sources, open flames, and direct sunlight, since the material is a volatile organic liquid. Chemically compatible glass bottles with secure caps are suitable, and containers should be resealed promptly after each use to limit evaporation and moisture uptake, which can promote hydrolysis of the ester group. Handle in a fume hood or a well-ventilated workspace, and wear standard laboratory protection including safety goggles, a laboratory coat, and chemically resistant gloves. Avoid contact with skin and eyes and avoid breathing vapour. Keep the material separated from strong oxidising agents, strong acids, and strong bases. Label all secondary containers clearly, and consult the manufacturer's safety data sheet before use and before disposal of residues.
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