[(Vinyloxy)methyl]benzene, commonly known as benzyl vinyl ether, is an electron-rich vinyl ether used widely in polymer and synthetic chemistry. It serves as a classical monomer for cationic polymerisation, giving poly(vinyl ether)s whose benzyl groups can later be removed by hydrogenolysis. In organic synthesis it acts as an electron-rich alkene in cycloadditions and as a convenient acetal-forming hydroxyl protecting reagent. TCI supplies the material in 5 g and 25 g pack sizes for laboratory research use.
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- Du et al. (1999). Vinyl monomers bearing chromophore moieties and their polymers. VIII. synthesis and fluorescence behavior of a vinyloxy monomer having an electron-accepting chromophore moiety,p-((vinyloxy)methyl)benzonitrile, and its polymers. Journal of Polymer Science Part A: Polymer Chemistry doi:10.1002/(sici)1099-0518(19990115)37:2<179::aid-pola8>3.0.co;2-4
- Nedolya et al. (2017). New aromatization pathway of 2,3-dihydropyridines by the action of superbase: Concurrent synthesis of 2-(methylsulfanyl)-6-[(vinyloxy)methyl]pyridine and 3-methoxy-6-methyl-2-(methylsulfanyl)pyridine. Russian Journal of Organic Chemistry doi:10.1134/s1070428017010262
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