Lithium Bis(pentafluoroethanesulfonyl)imide TCI L0267

Chemical Identity

Other names: Li (CF3CF2SO2)2N
CAS No.: 132843-44-8
PubChem: CID 12096715·SID 253661885
Formula: C4F10LiNO4S2
Molecular weight: 387.1 g/mol
Purity: >98.0%(T)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: lithium bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide
SMILES: [Li+].C(C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(C(F)(F)F)(F)F)(F)(F)F
InChIKey: ACFSQHQYDZIPRL-UHFFFAOYSA-N

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Lithium Bis(pentafluoroethanesulfonyl)imide (LiBF₄) is an inorganic salt widely used in chemical reactions, particularly in catalysis and inorganic chemistry. This compound plays a crucial role in laboratory settings by serving as an effective electrolyte in electrochemical systems. Its strong ionic properties make it a valuable component in various experimental setups, where it facilitates ion transfer and enhances reaction efficiency. Due to its stability and consistent performance, LiBF₄ is a reliable choice for researchers working on complex chemical processes that require precise control over ionic behavior.

One of the key reasons LiBF₄ is preferred is its high melting point, which ensures stability under a wide range of temperatures. Additionally, it exhibits excellent electrochemical properties, making it ideal for applications such as battery development and electroplating. The compound’s non-corrosive nature under normal conditions also contributes to its safety profile, allowing it to be used in laboratory environments with proper handling. These characteristics collectively make LiBF₄ a versatile and dependable material for both academic and industrial research.

In Indonesian laboratories, LiBF₄ is commonly used in electrochemical research and development. Its role in creating stable electrolyte solutions is vital for experiments involving voltaic cells and battery systems. The compound’s reliability and consistent performance make it a staple in chemical laboratories, supporting a variety of applications that require stable and efficient ionic behavior. Its widespread use underscores its importance in both teaching and research settings across Indonesia.

TCI brochures (PDF)

Practical Lithium Ion Battery Electrolytes with Low Water Content 2024-10-23 · p. 1
Lithium Electrolytes 2026-04-06 · p. 1
Lithium Compounds for Research and Experimental Use 2026-02-10 · p. 2
Lithium Battery Research Reagents 2026-06-04 · p. 2
Solar Cell Materials 2026-04-21 · p. 10
Metallic Salts 2025-11-06 · p. 13

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Electrochemical research utilizes LiBF₄ as a stable electrolyte for voltaic cell experiments due to its high ionic conductivity and thermal stability.
Battery development benefits from LiBF₄’s ability to maintain consistent ion transfer, essential for creating efficient and reliable power storage systems.
Electroplating processes rely on LiBF₄ to provide a stable and conductive medium, enhancing the quality and uniformity of metal coatings.
Catalytic reactions in inorganic chemistry often incorporate LiBF₄ to facilitate ion transfer, thereby increasing reaction efficiency and selectivity.
Analytical chemistry applications use LiBF₄ in electrochemical sensors to ensure accurate and reproducible measurements under controlled conditions.

Brand	TCI
CAS number	132843-44-8
Molecular formula	—
Purity	—
Category	Chemistry > Catalysis and Inorganic Chemistry > Main-group Elements
Pack sizes	Available in standard laboratory quantities as per supplier specifications
Physical form	Solid powder
Storage	Store in a cool, dry place away from moisture and incompatible substances

LiBF₄ should be stored in a cool, dry environment to maintain its stability and prevent degradation. It is recommended to use airtight containers to protect it from moisture and air exposure. Due to its non-corrosive nature under normal conditions, it is generally safe to handle with standard laboratory precautions. However, care should be taken to avoid direct contact with skin and eyes, and appropriate personal protective equipment should be worn during handling. The compound should be kept away from incompatible materials to ensure long-term stability and safety in the laboratory setting.

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