• 929896-28-6 Bis(acetato)aqua[(S,S)-4,6-bis(4-isopropyl-2-oxazolin-2-yl)-m-xylene]rhodium - AMI Scientific
  • 929896-28-6 Bis(acetato)aqua[(S,S)-4,6-bis(4-isopropyl-2-oxazolin-2-yl)-m-xylene]rhodium - AMI Scientific
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TCI

CAS 929896-28-6

Bis(acetato)aqua[(S,S)-4,6-bis(4-isopropyl-2-oxazolin-2-yl)-m-xylene]rhodium TCI B4195

Bis(acetato)aqua[(S,S)-4,6-bis(4-isopropyl-2-oxazolin-2-yl)-m-xylene]rhodium TCI B4195

Chemical Identity

CAS No.
929896-28-6
PubChem
CID 91972067·SID 253659893
Formula
C24H35N2O7Rh
Molecular weight
566.4 g/mol
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
(4S)-2-[2,4-dimethyl-5-[(4S)-4-propan-2-yl-4,5-dihydro-1,3-oxazol-2-yl]benzene-6-id-1-yl]-4-propan-2-yl-4,5-dihydro-1,3-oxazole;rhodium(3+);diacetate;hydrate
SMILES
CC1=CC(=C([C-]=C1C2=N[C@H](CO2)C(C)C)C3=N[C@H](CO3)C(C)C)C.CC(=O)[O-].CC(=O)[O-].O.[Rh+3]
InChIKey
OQNBPDKKWBPKGQ-VKBKZCJQSA-L
Rp 6.413.400,00
Rp 6.413.400,00
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Bis(acetato)aqua[(S,S)-4,6-bis(4-isopropyl-2-oxazolin-2-yl)-m-xylene]rhodium (CAS 929896-28-6) is a high-quality chemical from TCI, supplied as Reagent Grade.

Application: Synthesis reagent for a wide range of organic chemistry transformations in laboratory and industrial settings.

Specifications:

  • Molecular formula: C24H35N2O7Rh
  • CAS number: 929896-28-6
  • TCI product code: B4195

Available from AMI Scientific, the authorised TCI distributor in Indonesia. Contact us for pricing and stock availability — we ship throughout Indonesia.

Advantages (TCI brochure)

  • Converts terminal alkenes into optically active 1,2-diols
  • Catalyzes cross-coupling of alkynes in the formation of stereoselective ene-ynes

TCI brochures (PDF)

Related TCI products

From the TCI brochure

  • Asymmetric diboration of terminal alkenes and conversion to optically active 1,2-diols
  • Stereoselective cross-coupling of alkynes

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Data from the TCI brochure

Kemasan10 mg
Loading katalis1 mol% (THF, 60 °C, 1 h (diborasi))
Loading katalis1 mol% (H2 (1 atm), toluene, 100 °C, 4 h (kopling silang))

Source: TCI brochure RR032 (2024-08-07)

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References cited in the TCI brochure

  1. Jun-ichi Ito. Asymmetric Catalysis Mediated by Optically Active Bis(oxazolinyl)phenyl Metal Complexes Journal of Synthetic Organic Chemistry, Japan, 2013. doi:10.5059/yukigoseikyokaishi.71.791
  2. Kenji Toribatake. Asymmetric Diboration of Terminal Alkenes with a Rhodium Catalyst and Subsequent Oxidation: Enantioselective Synthesis of Optically Active 1,2‐Diols Angewandte Chemie International Edition, 2013. doi:10.1002/anie.201305181
  3. Jun-ichi Ito. Cross-Coupling of Alkynes Catalyzed by Phebox−Rhodium Acetate Complexes Organometallics, 2007. doi:10.1021/om700742t

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