1-[(tert-Butoxycarbonyl)amino]cyclohexanecarboxylic Acid TCI B6437

Chemical Identity

Other names: 1-(Boc-Amino)cyclohexanecarboxylic Acid · 1-[(tert-Butoxycarbonyl)amino]cyclohexane-1-carboxylic Acid
CAS No.: 115951-16-1
PubChem: CID 2794744
Formula: C12H21NO4
Molecular weight: 243.30 g/mol
Purity: >97.0%(GC)(T)
Storage: 0-10°C
Reference databases: ECHA

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: 1-[(2-methylpropan-2-yl)oxycarbonylamino]cyclohexane-1-carboxylic acid
SMILES: CC(C)(C)OC(=O)NC1(CCCCC1)C(=O)O
InChIKey: URBHKVWOYIMKNO-UHFFFAOYSA-N
MDL: MDL00273427

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TCI B6437 1-[(tert-Butoxycarbonyl)amino]cyclohexanecarboxylic Acid (CAS 115951-16-1) is a Boc-protected cyclic amino acid in which the amino and carboxyl groups share a quaternary carbon. Its rigid cyclohexane framework makes it valuable for designing conformationally constrained peptides and peptide analogues. The pre-installed Boc group saves a protection step and can be removed under well-established acidic conditions. Store the solid tightly sealed in a cool, dry place away from strong acids, and refer to the manufacturer's safety data sheet before handling.

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Amino Acids and Peptide Synthesis Reagents 2025-08-14 · p. 15

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Badland et al. (2010). An improved synthesis of (1R,3S)-3-[(tert-butoxycarbonyl)amino]cyclohexanecarboxylic acid. Tetrahedron: Asymmetry doi:10.1016/j.tetasy.2010.04.049
Kadyrov et al. (2021). Convenient Synthesis of (R)-3-[(tert-Butoxycarbonyl)amino]piperidine and (R)-3-[(tert-Butoxycarbonyl)amino]azepane. Synthesis doi:10.1055/a-1526-7657
(2012). Discussion Addendum For: Efficient Asymmetric Synthesis of N-tert-Butoxycarbonyl a-Amino Acids using 4-tert-Butoxycarbonyl-5,6-Diphenylmorpholin-2-one:. Organic Syntheses doi:10.15227/orgsyn.089.0394

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.