TCI C1383 Carbonylhydridotris(triphenylphosphine)rhodium(I) (CAS 17185-29-4) is a well known rhodium(I) complex for homogeneous catalysis. Its hydride, carbonyl, and triphenylphosphine ligand set supports oxidative addition and reductive elimination steps, making it effective for C–H activation chemistry. Typical applications include hydroacylation, decarbonylation, hydroformylation, and hydrosilylation, as well as mechanistic organometallic studies. AMI Scientific supplies this TCI catalyst in 1 g and 5 g packs; handling under inert atmosphere is recommended.
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- Wu et al. (1992). A phosphorus-31 NMR study of solid carbonylhydridotris(triphenylphosphine)rhodium(I). Unusual MAS sideband intensities in second-order NMR spin systems. Canadian Journal of Chemistry doi:10.1139/v92-114
- Balch et al. (1993). Structural characterization of {(.eta.2-C60)RhH(CO)(PPh3)2}: product of the reaction of fullerene C60 with the hydrogenation catalyst carbonylhydridotris(triphenylphosphine)rhodium. Inorganic Chemistry doi:10.1021/ic00069a001
- Babra et al. (1993). The crystal and molecular structure of a new polymorph of carbonylhydridotris(triphenylphosphine)rhodium(I) having a Rh-H stretching absorption at 2013 cm?1. Journal of Crystallographic and Spectroscopic Research doi:10.1007/bf01185550
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
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