Carbonylhydridotris(triphenylphosphine)rhodium(I) TCI C1383

Chemical Identity

Other names: Carbonyltris(triphenylphosphine)rhodium(I) Hydride · Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride
CAS No.: 17185-29-4
PubChem: CID 6101629·SID 87566394
Formula: C55H46OP3Rh
Molecular weight: 918.80 g/mol

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: carbon monoxide;hydride;rhodium;tris(triphenylphosphane)
SMILES: [H-].[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Rh]
InChIKey: LNIBUINQDXTYPF-UHFFFAOYSA-N
MDL: MDL00151644

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Berat 1g 5g

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TCI C1383 Carbonylhydridotris(triphenylphosphine)rhodium(I) (CAS 17185-29-4) is a well known rhodium(I) complex for homogeneous catalysis. Its hydride, carbonyl, and triphenylphosphine ligand set supports oxidative addition and reductive elimination steps, making it effective for C–H activation chemistry. Typical applications include hydroacylation, decarbonylation, hydroformylation, and hydrosilylation, as well as mechanistic organometallic studies. AMI Scientific supplies this TCI catalyst in 1 g and 5 g packs; handling under inert atmosphere is recommended.

TCI brochures (PDF)

C-H Bond Activation Reaction 2025-06-20 · p. 5
Transition Metal Catalysts 2026-04-10 · p. 10

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Wu et al. (1992). A phosphorus-31 NMR study of solid carbonylhydridotris(triphenylphosphine)rhodium(I). Unusual MAS sideband intensities in second-order NMR spin systems. Canadian Journal of Chemistry doi:10.1139/v92-114
Balch et al. (1993). Structural characterization of {(.eta.2-C60)RhH(CO)(PPh3)2}: product of the reaction of fullerene C60 with the hydrogenation catalyst carbonylhydridotris(triphenylphosphine)rhodium. Inorganic Chemistry doi:10.1021/ic00069a001
Babra et al. (1993). The crystal and molecular structure of a new polymorph of carbonylhydridotris(triphenylphosphine)rhodium(I) having a Rh-H stretching absorption at 2013 cm?1. Journal of Crystallographic and Spectroscopic Research doi:10.1007/bf01185550

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.