Collection: Asymmetric Hydrogenation Catalysts

Asymmetric Hydrogenation Catalysts — collects chiral transition metal complexes based on phosphine or salen ligands, such as DENEB derivatives, BINAP-ruthenium, and chiral cobalt salen complexes, which function as catalysts in asymmetric hydrogenation reactions. Chirality in the supporting ligand determines the enantiomeric selectivity of the resulting product.

These catalysts are used by synthetic organic chemists in asymmetric hydrogenation reactions of ketones, imines, or substituted olefins to produce chiral compounds with high enantiomeric selectivity. Ruthenium-BINAP complexes are commonly used in hydrogenation of beta-functional ketones, while chiral cobalt salen catalysts are utilized in asymmetric hydrogenation of certain olefin substrates in synthetic methodology research.

Example products in this collection: TCI T3078 1333981-84-2 (R,R)-Ts-DENEB(regR), TCI D2130 112022-83-0 (R)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine, TCI T3077 1384974-37-1 (S,S)-Ts-DENEB(regR), TCI D2131 112022-81-8 (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine, TCI B3067 132071-87-5 [(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride, TCI D5911 112022-83-0 (R)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine (ca. 1mol/L in Toluene), TCI B2315 259259-80-8 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II), TCI D5912 112022-81-8 (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine (ca. 1mol/L in Toluene).

Pay attention to the chiral configuration (R or S) of the catalyst that matches the enantiomer of the target product, as well as the stability of the metal complex toward air and the solvents used in the reaction procedure. All products are genuine products of Tokyo Chemical Industry (TCI) Japan, with purity, packaging, and storage conditions listed on each item's page.

Other parallel categories under Hydrogenation [Catalysis], often used together in one laboratory workflow:

• Hydrogenation Catalysts
• Transition Elements [Catalysis and Inorganic Chemistry]
• Metallic Salts [Catalysis and Inorganic Chemistry]
• Nitrogen-Donor Ligands [Catalysis]
• Main-group Elements [Catalysis and Inorganic Chemistry]
• Cross-coupling Reaction using Transition Metal Catalysts [C-C Bond Formation]

Back to Hydrogenation [Catalysis]. For large-volume procurement, special packaging, or specific grades, contact the AMI Scientific team — official TCI Japan distributor in Indonesia — to check availability and lead time directly from Japan.