TCI C0176 Benzyl Chloroformate (30–35% in Toluene), CAS 501-53-1, is a widely used acylating reagent for introducing the Cbz (benzyloxycarbonyl) protecting group onto amines. Supplied as a toluene solution in a 25 mL pack, it is convenient to measure and dispense for research-scale organic and peptide synthesis. The resulting carbamates are stable under many reaction conditions yet can be removed by hydrogenolysis, supporting orthogonal protection strategies. Handle it in a fume hood with appropriate protective equipment, keep the container tightly closed, and store it in a cool, dry, well-ventilated area away from ignition sources.
TCI brochures (PDF)
- Protecting Agents 2025-03-25 · p. 10
- Reagents for Glyco Chemistry & Biology 5th Edition · p. 130
- Amino Acids and Peptide Synthesis Reagents 2025-08-14 · p. 40
Related TCI products
- TCI B3021 501-53-1 Benzyl Chloroformate
- TCI C0795 17341-93-4 2,2,2-Trichloroethyl Chloroformate
- TCI F0197 28920-43-6 9-Fluorenylmethyl Chloroformate [N-Protecting Agent for Peptides Research]
- TCI B0105 98-88-4 Benzoyl Chloride
- TCI B0078 93-97-0 Benzoic Anhydride
- TCI C1124 13139-17-8 N-Carbobenzoxyoxysuccinimide
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- Lezama et al. (2014). Kinetics of the Gas-Phase Elimination Reaction of Benzyl Chloroformate and Neopentyl Chloroformate. International Journal of Chemical Kinetics doi:10.1002/kin.20896
- Pati et al. (2004). Synthesis of N‐Benzylated Anilines from the Reaction of Anilines and Benzyl Chloroformate.. ChemInform doi:10.1002/chin.200431064
- Mizuno et al. (2003). Non‐phosgene Synthesis of Benzyl Chloroformate (CbzCl).. ChemInform doi:10.1002/chin.200301081
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
Product Categories
- Building BlocksNon-Heterocyclic Building BlocksCarbonyl Compounds [Non-Heterocyclic Building Blocks]
- Chemical BiologyPeptide ChemistryAmine Protection [Peptide Chemistry]
- Chemical BiologyGlycoscienceReagents for Oligosaccharide Synthesis [Glycoscience]
- Synthetic ReagentsProtection, Deprotection, DerivatizationProtecting and Derivatizing Reagents [Synthetic Reagents]
- Pharmaceutical Development and Drug Discovery Research ReagentsPeptide ChemistryAmine Protection [Peptide Chemistry]
Produk Terkait
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BenzylChloroformate TCI B3021
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N-Carbobenzoxyoxysuccinimide TCI C1124
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